ASTM D6735-01(2009)

1.1 This method will measure the concentration of gaseous hydrochloric and hydrofluoric acids, and other gaseous chlorides and fluorides that pass through a particulate matter filter maintained at 177°C (350°F). This method is specific for sampling combustion effluent from mineral calcining industries and other stationary sources where the reactive/adsorptive nature of the particulate matter may affect measurements.

1.2 This method utilizes ion chromatography to quantify the aqueous samples, and thus measures only the C1^- and F^- ions.

1.3 Based on a one-hour sampling run, the method will provide results of known accuracy and precision for chloride and fluoride in-stack concentrations of 0.5 ppm (v) dry or greater. Extending the run duration and sampling a greater volume of effluent will extend the range to lower concentrations.

1.4 This method includes optional post-test quality assurance procedures to assess the bias of the test results, and optional paired sample train runs to assess the precision of test results.